Hi,
The transmission structure is not an output of RTTOV-SCATT, and the emissivity retrieval terms structure only contains total atmospheric transmittances, not level-to-space transmittances.
Unfortunately it is not possible to obtain level-to-space transmittances from RTTOV-SCATT. You can obtain clear-sky transmittances by running the same simulation in RTTOV (and if using v13.1 or v13.2 you can set opts%rt_all%transmittances_only to true for faster calculations). These are transmittances for the RTTOV pressure levels, not the RTTOV-SCATT pressure half-levels.
There is not currently any way to obtain cloudy transmittances from RTTOV-SCATT.
Best wishes,
James