Hi Andrey,
You must use an optical depth coefficient file (“rtcoef” file) that supports variable SO2. For RTTOV v13, these are indicated by having “7gas” in the filename indicating that they allow all 7 variable gases currently supported by RTTOV to vary. I would also recommend using the v13predictor file, rather than the older v9 predictors for variable SO2 simulations.
If this does not help let me know, and we can investigate further.
Best wishes,
James